methane isnt used in industry because it isnt as easy to use as other natural gases because it is a very stable hydrocarbon.
in fact ethane is the only hydrocarbon more stable than methane and ethane is a gaseous form of pure alchohol.
to create energy you must burn the fuel to create steam to turn the turbines, but methane is not flammable enough. it is very boring chemistry and proves that any one who has ever said they've lighted a fart before is lying!